In the case that the condensed matter contains other components, the equilibrium vapor pressure should have a different value. Here, let the equilibrium vapor pressure of a component A in a multi-component condensed matter at standard pressure be PA∅. Even in such a case, chemical potentials of a component A of a condensed phase and coexisting gas are equal. Therefore:
(3)
where μcond,A is the chemical potential of a component A with a fraction xA in a multi-component condensed matter. Chemical potential of a component A in a multi-component condensed matter, μcond,A, is expressed using chemical component of a pure condensed matter, μcond,A*
(4)
Now we define a quantity, activity, aA, as follows:
(5)
Eq. (4) is expressed using Eq. (5) as follows:
(6)
Since activity should be a function of a mole fraction of a component in a multi-component condensed matter, we relate the activity and mole fraction using a quantity, activity coefficient, γA as follows:
(7)
Using Eqs. (6) and (7), chemical potential of component A in a multi-component condensed matter is expressed as a function of its molar fraction xA:
(8)